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Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/491

Title: Study of the structure and electrostrictive property of proton-irradiated P(VDF-TrFE) 56/44 mol% copolymer
Authors: Lau, Sien Ting
Chan, Helen L. W.
Choy, Chung-loong
Subjects: P(VDF-TrFE)
Irradiation
Relaxor
Phase transition
Electrostriction
Copolymer
Polarization
Permittivity
Ferroelectric
Issue Date: Apr-2004
Publisher: IEEE
Citation: IEEE transactions on dielectrics and electrical insulation, Apr. 2004, v. 11, no. 2, p. 210-217.
Abstract: High-energy proton(3 MeV) irradiation with dosages ranging from 43 to 200 Mrad have been carried out to investigate the potential for modifying both the structure and property of vinylidene fluoride-trifluoroethylene 56/44 mol% copolymer. The structural and transitional behavior of the irradiated copolymer was studied by X-ray diffraction and differential scanning calorimetry. The polarization hysteresis, relative permittivity properties and electrostrictive strain response of these copolymers were also measured. It was found that the ferroelectric copolymer could be successfully converted to a relaxor at a low proton dosage of about 75 Mrad at ambient temperature. A slim polarization hysteresis loop and a frequency dispersion of the relative permittivity observed in the irradiated copolymer imply that the high-energy protons break up the coherent polarization domains in the ferroelectric copolymer into nano-sized regions. In addition, the irradiation leads to a significant change in the ferroelectric-to-paraelectric phase transition behavior. X-ray diffraction measurements show that the crystalline region in the copolymer is converted into a nonpolar phase upon irradiation, and the lattice spacing increases significantly. The electric field induced phase transformation of the nano-sized regions between the nonpolar and polar phase leads to a high electrostrictive strain observed in the irradiated copolymer.
Rights: © 2004 IEEE. Personal use of this material is permitted. However, permission to reprint/republish this material for advertising or promotional purposes or for creating new collective works for resale or redistribution to servers or lists, or to reuse any copyrighted component of this work in other works must be obtained from the IEEE.
This material is presented to ensure timely dissemination of scholarly and technical work. Copyright and all rights therein are retained by authors or by other copyright holders. All persons copying this information are expected to adhere to the terms and constraints invoked by each author's copyright. In most cases, these works may not be reposted without the explicit permission of the copyright holder.
Type: Journal/Magazine Article
URI: http://hdl.handle.net/10397/491
ISSN: 10709878
Appears in Collections:MRC Journal/Magazine Articles
AP Journal/Magazine Articles

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