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Title: Raman scattering, electronic, and ferroelectric properties of Nd modified Bi₄Ti₃O₁₂nanotube arrays
Authors: Zhou, Di
Gu, Haoshuang
Hu, Yongming
Qian, Zheli
Hu, Zhenglong
Yang, Kun
Zou, Yanan
Wang, Zhao
Wang, Yu
Guan, Jianguo
Chen, Wanping
Subjects: Bismuth compounds
Dielectric polarisation
Electronic structure
Ferroelectric materials
Leakage currents
Raman spectra
Sol-gel processing
Issue Date: 1-May-2010
Publisher: American Institute of Physics
Source: Journal of applied physics, 1 May 2010, v. 107, no. 9, 094105, p. 1-6.
Abstract: Neodymium-modified bismuth titanate, Bi₄−᙮Nd᙮Ti₃O₁₂(BNdT) , nanotube arrays were fabricated by sol-gel method utilizing experimentally prepared porous anodic aluminum oxide (AAO) templates with pore diameters of about 200 nm and 100 nm, respectively. The as-prepared nanotube arrays exhibit orthorhombic perovskite polycrystalline structure of BNdT, which have outer diameters of about 200 and 100 nm, corresponding to the pores diameters of the AAO templates employed, and with wall thicknesses of about 9.7 nm and 12 nm, respectively. The phonon vibration modes corresponding to the Bi atoms in the Bi₂O₂layers weaken and broaden with increasing Nd content. The changes of Raman internal modes originated from the vibrations of atoms inside the TiO₆ octahedral indicate the increase in octahedron tilting and structural distortion. The leakage current and polarization-electric field response curves of BNdT nanotube arrays were measured, and the hysteresis loop illustrates a good ferroelectric property of as-prepared BNdT nanotube array at room temperature. The dielectric constant and dissipation factor were measured in the frequency region from 1 kHz to 1 MHz indicating polarization relaxation phenomenon.
Rights: © 2010 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in D. Zhou et al., J. Appl. Phys. 107, 094105 (2010) and may be found at
Type: Journal/Magazine Article
DOI: 10.1063/1.3407563
ISSN: 0021-8979 (print)
1089-7550 (online)
Appears in Collections:MRC Journal/Magazine Articles
AP Journal/Magazine Articles

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