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Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/2449

Title: Enhanced photocatalytic activity of TiO₂by doping with Ag for degradation of 2,4,6-trichlorophenol in aqueous suspension
Authors: Rengaraj, S.
Li, Xiang-zhong
Subjects: Ag doping
Photodegradation
Sol–gel
TiO₂
2,4,6-trichlorophenol
UV light
Issue Date: 2-Jan-2006
Publisher: Elsevier
Citation: Journal of molecular catalysis A: Chemical, 2 Jan. 2006, v. 243, no. 1, p. 60-67.
Abstract: A series of Ag-TiO₂ nanocatalysts were synthesized by a sol–gel method with a doping content up to 2 wt%-Ag. The physico-chemical characteristics of the synthesized catalysts were characterized by X-ray diffraction, X-ray photoelectron emission spectroscopy, transmission electron microscopy, UV–vis absorption spectrometer, and optical ellipsometry to study the influence of the Ag content on the surface properties, optical absorption and other characteristics of the photocatalysts. The photocatalytic activity of the Ag-TiO₂was evaluated in the 2,4,6-trichlorophenol (TCP) degradation and mineralization in aqueous solution under UV-A illumination. The experiments demonstrated that TCP was effectively degraded by more than 95% within 120 min. It was confirmed that the presence of Ag on TiO₂catalysts could enhance the photocatalytic oxidation of TCP in aqueous suspension and the experimental results showed that the kinetics of TCP degradation follows a pseudo-first-order kinetic model. It was found that an optimal dosage of 0.5 wt% Ag in TiO₂achieved the fastest TCP degradation under the experimental conditions. The experimental results of TCP mineralization indicated while total organic carbon was reduced by a high portion of up to 80% within 120 min, most chlorine on TCP was more quickly converted to chloride within the first 40 min. On the basis of various characterizations of the photocatalysts, the reactions involved to explain the photocatalytic activity enhancement due to Ag doping include a better separation of photogenerated charge carriers and improved oxygen reduction inducing a higher extent of degradation of aromatics.
Description: DOI: 10.1016/j.molcata.2005.08.010
Rights: Journal of Molecular Catalysis A: Chemical © 2005 Elsevier B. V. The journal web site is located at http://www.sciencedirect.com.
Type: Journal/Magazine Article
URI: http://hdl.handle.net/10397/2449
ISSN: 1381-1169
Appears in Collections:CEE Journal/Magazine Articles

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